This project developed novel sampling tools to allow time integrated passive sampling of existing and emerging chemicals pollutants. Sampling devices developed through this work assisted with more comprehensive and cost-effective monitoring of newly recognised potential toxicants in surface and treated water across Australia.

Honours Thesis completed by Sarit Kaserzon in 2014.

Wastewater recycling uses reverse osmosis (RO) membranes to produce freshwater but this process also generates a waste stream – the reverse osmosis concentrate (ROC) – which contains almost all the contaminants present in the original wastewater. The disposal of untreated ROC poses a health and environmental risk. This research used 18 samples of ROC to test various treatment combinations and concluded that coagulation with ferric chloride followed by filtration with biological activated carbon reduced dissolved organic carbon, phosphorus and nitrogen compounds, and disinfection by-products, to safe and acceptable levels.

Harmful pathogens and compounds must be removed from wastewater before it can be discharged to the environment or used for irrigation, and many source waters need salts removed to make them potable. Microfiltration and ultrafiltration membranes remove pathogens and unwanted chemicals but as they are used, they become fouled and blocked by particulates and compounds from the water being filtered, as well as by the formation of biofilm, and by chemical interactions between solutes and the membrane materials. Although the membranes are cleaned regularly, the cleaning chemicals themselves can cause a problem. This research characterised the damage that various cleaning regimens inflict on membranes made of different materials and examined the effects of progressive and consecutive stages of membrane aging and degradation on performance. It was concluded that the type of cleaning agent affects the mechanism of membrane degradation and the severity of membrane integrity loss. More information is needed regarding the cleaning protocols and agents used in industry. Information from this research can inform a generally applicable model to predict membrane aging and decline in performance.

Microscopic pathogens in drinking water pose a risk to public health. In Australia, chlorine or chloramine are used to inactivate these pathogens, to disinfect drinking water and prevent widespread outbreaks of debilitating illness in large populations. Although largely successful, problems arise when drinking water is contaminated by pathogens after being disinfected in the treatment plant but before reaching the customer. A variety of situations cause this, one being small pipe leaks which become a route for soil micro-organisms to get into drinking water. To prevent pathogen contamination in pipe networks, higher levels of disinfectants can be added at the treatment plant, or secondary disinfection can be administered in the pipe network. This research project produced a guidance manual which explains how to maintain and monitor effective disinfection levels in post-treatment pipelines, and the major challenges to maintaining effective disinfection.

Cyanobacterial blooms in surface waters are a source of cells, taste and odour compounds, and a range of toxins. This research optimised treatment processes for the removal and control of cyanobacteria and their metabolites from a range of source waters. It was concluded that pre-chlorination is not advisable when cyanobacteria are present, but that in some situation’s potassium permanganate is a viable alternative. Although all three tested coagulants; ferric chloride, aluminium chlorohydrate and aluminium sulphate (alum) removed 90 to 95% of cells, alum at pH 6.3 was the most cost-effective. Maintaining pH > 6 reduced cell lysis and metabolite release. Since cyanobacteria in sludge remained viable for 2-3 weeks it was recommended that sludge detention in the clarifiers should be minimised.

Water is disinfected to remove harmful organisms, then filtered and treated to remove contaminating pollutants. The treated water then enters distribution pipe networks which eventually terminate at customers taps. The distribution systems can be many kilometres long and if the drinking water is in the distribution system for extended periods of time, the activity of the disinfectant gradually declines. This project used a laboratory model of a representative distribution system to make changes to initial water treatment, then examined their effects on the maintenance of disinfection and water quality.

This paper discusses various water quality risk management techniques and proposes a step-by-step catchment risk assessment methodology that is compatible with the Australian Drinking Water Guidelines.