N-nitrosodiumdimethylamine (NDMA) in drinking water is one of many factors – such as a persons’ genes – that cause cancer. Although NDMA is not a sole cause of cancer, the water industry aims to minimise its contribution to illness and disease. This research measured levels of NDMA in drinking and recycled waters and found the majority well below the Australian Drinking Water Guideline values that are considered safe for public consumption. Different sources of NDMA were identified and water monitoring and treatment strategies to optimise NDMA removal from source waters were recommended.

Recycling wastewater by using reverse osmosis (RO) and ultrafiltration appears to be associated with the formation of some groups of micropollutants but there is not much information about these processes. This research selected iodinated disinfection by-products (DBPs) and N-nitrosamines (NDMA), and benzotriazoles and benzothiazoles, which are compounds in dishwasher detergents, for further investigation. It was concluded that minimising the formation of dichloramine (a precursor molecule to NDMA formation) by reducing pH and maximising activated sludge ammonia production, reduced the formation of N-nitrosamines in RO-treated wastewater. Iodinated DBPs and benzotriazoles were detected in RO treated wastewater in this study but at lower concentrations than those thought to pose a risk to human health.

Disinfection is essential for removing harmful microbial pathogens and making safe drinking water but can also cause formation of disinfection by-products (DBPs), some of which pose a health risk. Thirty years of research have amassed a wealth of knowledge about the identification, formation, treatment and control, toxicology and epidemiology of DBPs in Australia. This project compiled, assessed and presented an overview of DBP-related research in Australia.

Natural organic matter (NOM) and bromide in source waters react with disinfectants to produce disinfection by-products (DBPs) in drinking water. This research quantified NOM and bromine in raw water and after coagulation treatment with alum. Neither raw nor alum-treated water were toxic in two laboratory tests. This research used a new site to confirm previous findings (Project 1041) that coagulation reduces DBP formation and toxicity after chlorination.

Source waters are disinfected to remove harmful pathogens, but chlorine reacts with organic matter and bromides to form disinfection by-products (DBPs) which can affect health. Water treatment reduces DBPs to safe levels by using alum to remove organic matter before disinfection but some water sources, particularly those with high bromine levels, are still difficult to treat. This research aimed to compile the best protocols for alum coagulation and disinfection when source waters contain different levels of organic matter and bromides, and to relate these to health risks. When organic matter was removed with 125 mg/L alum, and this treated source water was disinfected twice, and the first dose was calculated to generate chlorine levels of 0.5 mg / L for two days before administering the second dose, then DBP levels in drinking water were minimised. Neither alum-treated nor disinfected water caused toxicity in two laboratory tests used to examine risks to health.

Components of dissolved organic matter (DOM) and dissolved organic nitrogen (DON) in source waters can react with disinfecting chlorine or chloramine to form nitrogenous disinfection byproducts (n-DBPs) which might be toxic and hazardous to health. In this research, water samples were collected from nine water treatment plants and found to contain 28 n-DBPs. Total n-DBP formation, and particularly brominated n-DBP formation, was affected more by the levels of bromine in raw water than the different forms of nitrogen, and this led to the recommendation that it could be beneficial to monitor raw waters with high bromine concentrations. Although chloramination caused formation of more n-DBPs than chlorination, coagulation treatment decreased total DBP levels. Further research was recommended to characterise the toxicity of n-DBPs and to optimise the removal of DOM, DON and other n-DBP precursors by using GAC Acticarb in the treatment train.

Chlorine removes harmful pathogens from water but has the disadvantage of forming disinfection by-products (DBPs) by reacting with organic matter sometimes found in water. Chloramine also disinfects, is less likely to form DBPs and is more stable, so remains active in for longer in the pipelines which distribute drinking water from the plant to the tap. The problem is that it is difficult to predict exactly how much chloramine to add; it needs to be enough to maintain disinfecting activity in the pipeline distribution system, but not so much that customers find the smell of chlorine in tap water unpleasant. Traditionally, the chemical reaction rate has been used to predict the gradual ‘decay’ of chloramine in pipelines, but this is inaccurate. This research developed a computer software statistical programme that uses ‘artificial neural network’ concepts and operations to predict the longevity of chloramine residuals in water distribution systems. This is more accurate than traditional methods.