Wastewater recycling uses reverse osmosis (RO) membranes to produce freshwater but this process also generates a waste stream – the reverse osmosis concentrate (ROC) – which contains almost all the contaminants present in the original wastewater. The disposal of untreated ROC poses a health and environmental risk. This research used 18 samples of ROC to test various treatment combinations and concluded that coagulation with ferric chloride followed by filtration with biological activated carbon reduced dissolved organic carbon, phosphorus and nitrogen compounds, and disinfection by-products, to safe and acceptable levels.

The ADWG prioritises the removal of microscopic pathogens (and the toxins some produce) from public drinking water supplies to prevent large scale outbreaks of illness. This principle underlies the importance of adhering to consistently high standards of water treatment plant (WTP) operation and maintenance. This Guide refers primarily to the conventional WTP processes of chemical pre-treatment, coagulation, flocculation, clarification, filtration and disinfection; and establishes target criteria and critical limits for each step in the treatment process. The Guide is designed to provide water utility managers and operations staff with a concise reference document to optimising the WTP processes that produce microbially-safe drinking water and additionally supports the establishment of microbial Health-based targets.

Water treatment plants (WTP) take in source waters then remove 95-99% of blue-green algae (cyanobacteria) cells and the toxins they produce. During this removal process waste sludge is generated and transferred from clarifier tanks in the treatment plant to lagoons. It was thought that confinement in the sludge killed the cyanobacteria, but this research found that when algal blooms have generated very high cell numbers, viable, toxin-producing cyanobacteria are retained in the sludge and can release toxins into the clarifier supernatant. It was concluded that timely removal to lagoons will avoid problems, and it is recommended that risk assessment for recycling lagoon supernatant back to the head of the WTP should incorporate extended times of 3 to 4 weeks after the end of algal blooms, to ensure cyanobacterial cell death and toxin degradation.

Natural organic matter (NOM) and bromide in source waters react with disinfectants to produce disinfection by-products (DBPs) in drinking water. This research quantified NOM and bromine in raw water and after coagulation treatment with alum. Neither raw nor alum-treated water were toxic in two laboratory tests. This research used a new site to confirm previous findings (Project 1041) that coagulation reduces DBP formation and toxicity after chlorination.

Components of dissolved organic matter (DOM) and dissolved organic nitrogen (DON) in source waters can react with disinfecting chlorine or chloramine to form nitrogenous disinfection byproducts (n-DBPs) which might be toxic and hazardous to health. In this research, water samples were collected from nine water treatment plants and found to contain 28 n-DBPs. Total n-DBP formation, and particularly brominated n-DBP formation, was affected more by the levels of bromine in raw water than the different forms of nitrogen, and this led to the recommendation that it could be beneficial to monitor raw waters with high bromine concentrations. Although chloramination caused formation of more n-DBPs than chlorination, coagulation treatment decreased total DBP levels. Further research was recommended to characterise the toxicity of n-DBPs and to optimise the removal of DOM, DON and other n-DBP precursors by using GAC Acticarb in the treatment train.

Cyanobacterial blooms in surface waters are a source of cells, taste and odour compounds, and a range of toxins. This research optimised treatment processes for the removal and control of cyanobacteria and their metabolites from a range of source waters. It was concluded that pre-chlorination is not advisable when cyanobacteria are present, but that in some situation’s potassium permanganate is a viable alternative. Although all three tested coagulants; ferric chloride, aluminium chlorohydrate and aluminium sulphate (alum) removed 90 to 95% of cells, alum at pH 6.3 was the most cost-effective. Maintaining pH > 6 reduced cell lysis and metabolite release. Since cyanobacteria in sludge remained viable for 2-3 weeks it was recommended that sludge detention in the clarifiers should be minimised.